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1] Maria Sharapova (RUS) v Anastasia Rodionova (AUS)
[Q] Vesna Dolonc (SRB) v Tsvetana Pironkova (BUL)
Hsieh Su-Wei (TPE) v [WC] Virginie Razzano (FRA)
Stephanie Foretz Gacon (FRA) v [29] Monica Niculescu (ROU)

[23] Petra Cetkovska (CZE) v Vania King (USA)
Sloane Stephens (USA) v [Q] Karolina Pliskova (CZE)
Bojana Jovanovski (SRB) v Eleni Daniilidou (GRE)
Petra Martic (CRO) v [15] Sabine Lisicki (GER)

[12] Vera Zvonareva (RUS) v Mona Barthel (GER)
Edina Gallovits-Hall (ROU) v Silvia Soler-Espinosa (ESP)
Chang Kai-Chen (TPE) v Andrea Hlavackova (CZE)
Kim Clijsters (BEL) v [18] Jelena Jankovic (SRB)

[28] Christina McHale (USA) v [WC] Johanna Konta (GBR)
Lesia Tsurenko (UKR) v Mathilde Johansson (FRA)
Ekaterina Makarova (RUS) v Alberta Brianti (ITA)
Lucie Hradecka (CZE) v [8] Angelique Kerber (GER)

[3] Agnieszka Radwanska (POL) v Magdalena Rybarikova (SVK)
Venus Williams (USA) v Elena Vesnina (RUS)
Iveta Benesova (CZE) v Heather Watson (GBR)
Jamie Hampton (USA) v [27] Daniela Hantuchova (SVK)

[20] Nadia Petrova (RUS) v [Q] Maria Elena Camerin (ITA)
Timea Babos (HUN) v [WC] Melanie Oudin (USA)
Tamarine Tanasugarn (THA) v Anna Tatishvili (GEO)
[Q] Camila Giorgi (ITA) v [16] Flavia Pennetta (ITA)

[11] Li Na (CHN) v Ksenia Pervak (KAZ)
Sorana Cirstea (ROU) v Pauline Parmentier (FRA)
[WC] Naomi Broady (GBR) v Lourdes Dominguez Lino (ESP)
Alexandra Cadantu (ROU) v [17] Maria Kirilenko (RUS)

[30] Peng Shuai (CHN) v [Q] Sandra Zaniewska (POL)
Jarmila Gajdosova (AUS) v Ayumi Morita (JPN)
Arantxa Rus (NED) v [LL] Misaki Doi (JPN)
Carla Suarez Navarro (ESP) v [5] Samantha Stosur (AUS)

[6] Serena Williams (USA) v Barbora Zahlavova Strycova (CZE)
Johanna Larsson (SWE) v [Q] Melinda Czink (HUN)
Vera Dushevina (RUS) v Aleksandra Wozniak (CAN)
Stephanie Dubois (CAN) v [25] Zheng Jie (CHN)

[19] Lucie Safarova (CZE) v Kiki Bertens (NED)
Chanelle Scheepers (RSA) v [WC] Yaroslava Shvedova (KAZ)
Laura Pous-Tio (ESP) v Anne Keothavong (GBR)
[Q] Coco Vandeweghe (USA) v [10] Sara Errani (ITA)

[13] Dominika Cibulkova (SVK) v Klara Zakopalova (CZE)
Olga Govortsova (BLR) v [Q] Annika Beck (GER)
Polona Hercog (SLO) v [Q] Kristyna Pliskova (CZE)
[WC] Laura Robson (GBR) v [24] Francesca Schiavone (ITA)

[31] Anastasia Pavlyuchenkova (RUS) v Sofia Arvidsson (SWE)
Patricia Mayr-Achleitner (AUT) v Varvara Lepchenko (USA)
Elena Baltacha (GBR) v Karin Knapp (ITA)
Akgul Amanmuradova (UZB) v [4] Petra Kvitova (CZE)

[7] Caroline Wozniacki (DEN) v Tamira Paszek (AUT)
Alize Cornet (FRA) v Nina Bratchikova (RUS)
Greta Arn (HUN) v Galina Voskoboeva (KAZ)
Yanina Wickmayer (BEL) v [32] Svetlana Kuznetsova (RUS)

[21] Roberta Vinci (ITA) v [WC] Ashleigh Barty (AUS)
Urszula Radwanska (POL) v Marina Erakovic (NZL)
[Q] Mirjana Lucic (CRO) v Alexandra Panova (RUS)
Casey Dellacqua (AUS) v [9] Marion Bartoli (FRA)

[14] Ana Ivanovic (SRB) v Maria Jose Martinez Sanchez (ESP)
Kimiko Date-Krumm (JPN) v Kateryna Bondarenko (UKR)
Anastasiya Yakimova (BLR) v Mandy Minella (LUX)
Shahar Peer (ISR) v [22] Julia Goerges (GER)

[26] Anabel Medina Garrigues (ESP) v Simona Halep (ROU)
[Q] Jana Cepelova (SVK) v [Q] Kristina Mladenovic (FRA)
Irina-Camelia Begu (ROU) v Romina Oprandi (SUI)
Irina Falconi (USA) v [2] Victoria Azarenka (BLR)